Starting with 3 zeroes leaves 2 bits for which there are 4 (22) combinations:
00000, 00001, 00010, 00011. These represent the decimal numbers 0-3.
Starting with 2 ones leaves 3 bits for which there are 8 (23) combinations:
11000, 11001, 11010, 11011, 11100, 11101, 11110, 11111. These represent the decimal numbers 24-31.
So there are 12 possible bit strings.